Rechtliche Information zum dekorativen Bild: UR / Julia Dragan
Our research activities revolve around the use of intermolecular interactions in the molecular design of chemosensors, catalysts and pharmaceutically active compounds. Design, synthesis and determination of properties are the typical elements of all projects. We currently focus on the following challenges:
- Molecular Recognition
- Chemical Photocatalysis
- Substainable Chemistry
- Medical Chemistry
Forschungsschwerpunkte
Publikationen
Publikationen
- Nikitin, Maksim, Ötvös, Sándor B., Ghosh, Indrajit, Philipp, Maximilian, Gschwind, Ruth, Kappe, C. Oliver und König, Burkhard (2025) Brønsted Acid-Facilitated Thioetherification Cross-Coupling Reactions with Nickel and Visible Light.
ACS Catalysis, S. 1467-1476.
https://dx.doi.org/10.1021/acscatal.4c06734 - Babawale, Florence, Ghosh, Indrajit und König, Burkhard (2025) C(sp2)-S Cross-Coupling Reactions with Adaptive Dynamic Homogeneous Catalysis: Synthesis of Ethyl 4-((3-Ethoxy-3-oxopropyl)thio)benzoate.
Organic Syntheses: 102, S. 128-142.
https://dx.doi.org/10.15227/orgsyn.102.0128 - Düker, Jonas, Philipp, Maximilian, Lentner, Thomas, Cadge, Jamie A., Lavarda, João E. A., Gschwind, Ruth M., Sigman, Matthew S., Ghosh, Indrajit und König, Burkhard (2024) Cross-Coupling Reactions with Nickel, Visible Light, and tert-Butylamine as a Bifunctional Additive.
ACS Catalysis, S. 817-827.
https://dx.doi.org/10.1021/acscatal.4c07185 - Taskinen, Elina K., Kolb, Daniel, Morgenstern, Martin und König, Burkhard (2024) Photocatalyzed Dehydration of 1‐Aryl‐1,2‐Ethanediols to Methyl Ketones Driven by Eosin Y Fragmentation Products.
Chemistry – A European Journal
https://dx.doi.org/10.1002/chem.202404200 - Grotjahn, Sascha und König, Burkhard (2024) Common ground and divergence: OLED emitters as photocatalysts.
Chemical Communications: 60, S. 12951-12963.
https://dx.doi.org/10.1039/D4CC04409F - Maleeva, Galyna, Nin-Hill, Alba, Wirth, Ulrike, Rustler, Karin, Ranucci, Matteo, Opar, Ekin, Rovira, Carme, Bregestovski, Piotr, Zeilhofer, Hanns Ulrich, König, Burkhard, Alfonso-Prieto, Mercedes und Gorostiza, Pau (2024-10-09) Light-Activated Agonist-Potentiator of GABAA Receptors for Reversible Neuroinhibition in Wildtype Mice.
Journal of the American Chemical Society: 146 (42), S. 28822-28831.
https://dx.doi.org/10.1021/jacs.4c08446 - Dauth, Bastian, Giusto, Paolo, König, Burkhard und Gschwind, Ruth M. (2024) In situ Monitoring of Photocatalysis on Polymeric Carbon Nitride Thin Films.
Angewandte Chemie, S. e202412972.
https://dx.doi.org/10.1002/anie.202412972 - Dauth, Bastian, Giusto, Paolo, König, Burkhard und Gschwind, Ruth M. (2024-12-09) In situ Überwachung photokatalytischer Prozesse mit polymeren Kohlenstoffnitrid‐Dünnschichtfilmen.
Angewandte Chemie: 136 (50), S. e202412972.
https://dx.doi.org/10.1002/ange.202412972 - Tian, Ya-Ming, Pu, Xiang, Heredero Sánchez, Alejandro, Silva, Wagner, Gschwind, Ruth M. und König, Burkhard (2024) Photoinduced Radical Borylation of Robust Carbon−Heteroatom Bonds.
Advanced Synthesis & Catalysis: 367 (2)
https://dx.doi.org/10.1002/adsc.202400547 - Singh, Puja, König, Burkhard und Shaikh, Aslam C. (2024) Electro-photochemical Functionalization of C(sp3)–H bonds: Synthesis toward Sustainability.
JACS Au: 4, S. 3340-3357.
https://dx.doi.org/10.1021/jacsau.4c00496 - Grotjahn, Sascha, Müller, Lea, Pattanaik, Aryaman, Falk, Alexander, Barison, Giorgia, Bauer, Jonathan O., Rehbein, Julia, Gschwind, Ruth M. und König, Burkhard (2024) Regio-, diastereo- and enantioselectivity in the photocatalytic generation of carbanions via hydrogen atom transfer and reductive radical-polar crossover.
Organic Chemistry Frontiers: 11 (20), S. 5890-5900.
https://dx.doi.org/10.1039/D4QO01219D - Lahmy, Ranit, Hiefinger, Caroline, Zeqiri, Fjoralba, Mandl, Sabrina, Straub, Kristina, Stockerl, Willibald J., Gschwind, Ruth M., Rudack, Till, König, Burkhard und Hupfeld, Andrea (2024) Promoting enzyme catalysis via azobenzene facilitated vibrational energy transfer.
biorxiv, S. preprint.
https://dx.doi.org/10.1101/2024.07.04.602025 - Kolb, Daniel, Friedmann, Kai und König, Burkhard (2024) Tandem Synthesis of Benzylidenemalononitrile Derivatives in/on Water under Visible Light.
ChemCatChem
https://dx.doi.org/10.1002/cctc.202400936 - Taskinen, Elina K., Kolb, Daniel, Morgenstern, Martin und König, Burkhard (2024) Data archive of "Photocatalytic dehydration of 1-aryl-1,2-ethanediols to methyl ketones via HAT-initiated spin-center shift".
- Lahmy, Ranit, Hübner, Harald, Gmeiner, Peter und König, Burkhard (2024) Covalent and Visible-Light Photoswitchable Derivatives of the Potent Synthetic Opioid Isotonitazene and Other Nitazenes.
ChemPhotoChem: 8 (7), S. e202400022.
https://dx.doi.org/10.1002/cptc.202400022 - Grotjahn, Sascha, Graf, Christina, Zelenka, Jan, Pattanaik, Aryaman, Müller, Lea, Kutta, Roger Jan, Rehbein, Julia, Roithová, Jana, Gschwind, Ruth M., Nuernberger, Patrick und König, Burkhard (2024) Reactivity of Superbasic Carbanions Generated via Reductive Radical‐Polar Crossover in the Context of Photoredox Catalysis.
Angewandte Chemie International Edition, S. e202302267.
https://dx.doi.org/10.1002/anie.202400815 - Tian, Ya-Ming, Silva, Wagner, Gschwind, Ruth Maria und König, Burkhard (2024) Accelerated photochemical reactions at oil-water interface exploiting melting point depression.
Science: 383 (6684), S. 750-756.
https://dx.doi.org/10.1126/science.adl3092 - Stahl, Jessica und König, Burkhard (2024) A Survey of the Iron Ligand-to-Metal Charge Transfer Chemistry in Water.
Green Chemistry: 26, S. 3058-3071.
https://dx.doi.org/10.1039/D3GC04595A - Benedetti Vega, Kimberly, Carvalho de Oliveira, André Luiz, König, Burkhard und Weber Paixão, Márcio (2024-02) Visible-Light-Induced Synthesis of 1,2-Dicarboxyl Compounds from Carbon Dioxide, Carbamoyl-dihydropyridine, and Styrene.
Organic Letters: 26 (4), S. 860-865.
https://dx.doi.org/10.1021/acs.orglett.3c04015 - Shlapakov, Nikita S., Kobelev, Andrey D., Burykina, Julia V., Kostyukovich, Alexander Yu., König, Burkhard und Ananikov, Valentine P. (2024) Reversible Radical Addition Guides Selective Photocatalytic Intermolecular Thiol-Yne-Ene Molecular Assembly.
Angewandte Chemie International Edition
https://dx.doi.org/10.1002/anie.202314208 - Nikitin, Maksim, Babawale, Florence, Tastekin, Sena, Antonietti, Markus und König, Burkhard (2024) C(sp2)–S cross-coupling reactions with nickel, visible light, and mesoporous graphitic carbon nitride.
Green Chemistry: 26, S. 5845-5851.
https://dx.doi.org/10.1039/D3GC04517J - Kiprova, Natalia, Desnoyers, Marine, Narobe, Rok, Klufts-Edel, Arthur, Chaud, Juliane, König, Burkhard, Compain, Philippe und Kern, Nicolas (2023) Towards a General Access to 1-Azaspirocyclic Systems via Photoinduced, Reductive Decarboxylative Radical Cyclizations.
Chemistry - A European Journal
https://dx.doi.org/10.1002/chem.202303841 - Stahl, Jessica, Reiter, Thilo und König, Burkhard (2024) Chemo-selective Vicinal Dichlorination of Alkenes by Iron Ligand-to-Metal Charge Transfer Catalysis.
Synlett: 2024 (1)
https://dx.doi.org/10.1055/a-2225-8858 - Delgado, José A. C., Tian, Ya-Ming, Marcon, Michela, König, Burkhard und Paixão, Márcio W. (2023) Side-Selective Solid-Phase Metallaphotoredox N(in)-Arylation of Peptides.
Journal of the American Chemical Society: 145 (48), S. 26452-26462.
https://dx.doi.org/10.1021/jacs.3c10792 - Wirth, Ulrike, Raabe, Konstantin, Kalaba, Predrag, Keimpema, Erik, Muttenthaler, Markus und König, Burkhard (2023) Photoswitchable Probes of Oxytocin and Vasopressin.
Journal of Medicinal Chemistry: 66, S. 14853-14865.
https://dx.doi.org/10.1021/acs.jmedchem.3c01415