Publications

A diazadiphospholenium cation featuring a reactive P=P bond: synthesis and reversible main-group bond activation

Abstract: We report a high-yielding synthesis of a novel diazadiphospholenium cation featuring a sterically exposed, reactive P=P bond. It displays aromatic properties and greater reactivity and selectivity than its parent diphosphene, enabling selective [4+2] cycloaddition and unusual, reversible E–E bond scission in diphenyldichalcogenides, highlighting its potential for main-group bond activation.

J. Wieneke, F. Cirigliano, M. Schorpp, Chem. Commun. 2025, 61, 17601–17604. DOI 10.1039/D5CC04820F. (externer Link, öffnet neues Fenster)

Cover Artwork: DOI 10.1039/D5CC90374B (externer Link, öffnet neues Fenster)

Pre-independence

R. Yadav, A. Maiti, M. Schorpp, J. Graf, F. Weigend, L. Greb, Nature Chemistry 2024, 16, 1523–1530.
N. Ansmann, J. Münch, M. Schorpp, L. Greb, Angew Chem Int Ed 2023, 62, e202313636.
J. M. Rall, M. Lapersonne, M. Schorpp, I. Krossing, Angew Chem Int Ed 2023, 62, e202312374.
R. Yadav, P. Janßen, M. Schorpp, L. Greb, J. Am. Chem. Soc. 2023, 145, 17746.
A. Billion, M. Schorpp, R. Feser, M. Schmitt, L. Eisele, H. Scherer, T. Sonoda, H. Kawa, B. Butschke, I. Krossing, Dalton Trans. 2023, 52, 4355.
N. Ansmann, D. Hartmann, S. Sailer, P. Erdmann, R. Maskey, M. Schorpp, L. Greb, Angew. Chem. Int. Ed. 2022, 61, e202203947.
J. M. Rall, M. Schorpp, M. Keilwerth, M. Mayländer, C. Friedmann, M. Daub, S. Richert, K. Meyer, I. Krossing, Angew. Chem. Int. Ed. 2022, 61, e202204080.
M. Schorpp, R. Yadav, D. Roth, L. Greb, Angew. Chem. Int. Ed. 2022, 61, e202207963.
M. Schorpp, R. Tamim, I. Krossing, Dalton Trans.* 2021, 50, 15103.
M. Hermann, T. Böttcher, M. Schorpp, S. Richert, D. Wassy, I. Krossing, B. Esser, Chem. Eur. J. 2021, 27, 4964.
P. Dabringhaus, M. Schorpp, H. Scherer, I. Krossing, Angew. Chem. Int. Ed. 2020, 59, 22023.
M. Schorpp, I. Krossing, Chem. Sci. 2020, 11, 2068.
M. Schorpp, T. Heizmann, M. Schmucker, S. Rein, S. Weber, I. Krossing, Angew. Chem. Int. Ed. 2020, 59, 9453.
M. Schorpp, I. Krossing, Chem. Sci. 2020, 11, 2068.
I. M. Riddlestone, S. Keller, F. Kirschenmann, M. Schorpp, I. Krossing, Eur. J. Inorg. Chem. 2019, 2019, 59.
I. M. Riddlestone, P. Weis, A. Martens, M. Schorpp, H. Scherer, I. Krossing, Chem. Eur. J. 2019, 25, 10546.
M. Schorpp, S. Rein, S. Weber, H. Scherer, I. Krossing, Chem. Commun. 2018, 54, 10036.

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