47. D. J. Scott, J. Cammarata, F. Westermair, P. Coburger, D. Duvinage, M. Janssen, M. K. Uttendorfer; J. Beckmann, R. M. Gschwind, R. Wolf, Angew. Chem. Int. Ed.. 2024, e202408423; „Unravelling White Phosphorus: Experimental and Computational Studies Reveal the Mechanisms of P4 Hydrostannylation”
DOI: 10.1002/anie.202408423
46. S. Yakubov, B. Dauth, W. J. Stockerl, W. da Silva, R. M. Gschwind, J. P. Barham, ChemSusChem. 2024, e202401057; „Protodefluorinated Selectfluor® Aggregatively Activates Selectfluor® for Efficient Radical C(sp3)−H Fluorination Reactions”
DOI: 10.1002/cssc.202401057
45. J. Eder, A. Antonov, E. Tupiklia, R. M. Gschwind, Chem. Eur. J. 2024, 30, e202401793; „Chiral Diselenophosphoric Acids for Ion Pair Catalysis: A Novel Approach to Enhance Both Proton Donating and Proton Accepting Properties”
DOI: 10.1002/chem.202401793
44. M. Hecht, P. Dullinger, W. Silva, D. Horinek, R. M. Gschwind, Chem. Sci. 2024, 15, 9104-9111; „Highly Acidic N-Triflylphosphoramides as Chiral Brønsted Acid Catalysts: The Effect of Weak Hydrogen Bonds and Multiple Acceptors on Complex Structures and Aggregation”
DOI: 10.1039/D4SC01939C
43. T. Huber, J. Bauer, Chem. Eur. J. 2024, 30, e202303760; „A Powerful P−N Connection: Preparative Approaches, Reactivity, and Applications of P-Stereogenic Aminophosphines”
DOI: 10.1002/chem.202303760
42. V. R. Landaeta, T. M. Horsley Downie, R. Wolf, Chem. Rev. 2024, 124, 1323-1463; „Low-Valent Transition Metalate Anions in Synthesis, Small Molecule Activation, and Catalysis”
DOI: 10.1021/acs.chemrev.3c00121
41. M. Gawron, F. Gilch, D. Schmidhuber, J. A. Kelly, T. M. Horsley Downie, A. Jacobi von Wangelin, J. Rehbein, R. Wolf, Angew. Chem. Int. Ed. 2024, 63, e202315381; „Counterion Effect in Cobaltate-Catalyzed Alkene Hydrogenation”
DOI: 10.1002/anie.202315381
40. S. Grotjahn, C. Graf, J. Zelenka, A. Pattanaik, L. Müller, R. J. Kutta, J. Rehbein, J. Roithová, R. M. Gschwind, P. Nuernberger, B. König, Angew. Chem. Int. Ed. 2024, 63, e202400815; „Reactivity of Superbasic Carbanions Generated via Reductive Radical-Polar Crossover in the Context of Photoredox Catalysis”
DOI: 10.1002/anie.202400815
39. Y.-M. Tian, W. Silva, R. M. Gschwind, B. König, Science 2024, 383, 750-756; „Accelerated Photochemical Reactions at Oil-Water Interface Exploiting Melting Point Depression”
DOI: 10.1126/science.adl3092
2023
38. P. Dullinger, D. Horinek, J. Am. Chem. Soc., 2023, 145, 24922-24930; „Solvation of Nanoions in Aqueous Solutions”
DOI: 10.1021/jacs.3c09494
37. B. N. Baumann, H. Lange, F. Seeberger, P. Büschelberger, R. Wolf, M. Hapke, Mol. Catal., 2023, 550, 113482; „Cobalt and iron metallates as catalysts for cyclization reactions of diynes and triynes: [2+2+2] Cycloaddition vs. Garratt-Braverman reaction”
DOI: 10.1016/j.mcat.2023.113482
36. J, Gramüller, R. M. Gschwind, Acc. Chem. Res., 2023, 56, 2968-2979; „An NMR Spectroscopy View on London Dispersion in Catalysis: Detection, Quantification and Application in Ion Pair and Transition Metal Catalysis”
DOI: 10.1021/acs.accounts.3c00431
35. V. George, B. König, Chem. Commun., 2023, 59, 11835-11838; „S Photogenerated donor–donor diazo compounds enable facile access to spirocyclopropanes”
DOI: 10.1039/D3CC03581F
34. P. A. Braun, F. Westermair, R. M. Gschwind, N. Korber, Z. Anorg. Allg. Chem., 2023, 649, e20230017; „(K,Rb)@([2.2.2]crypt)]2(K,Rb)4[Si9W(CO)4] ⋅ 13.4 NH3 – The First Tungsten Functionalized Silicon Zintl Cluster”
DOI: 10.1002/zaac.202300117
33. L. Wylie, J. P. Barham, B. Kirchner ChemPhysChem, 2023, e202300470; „Solvent Dependency of Catalyst-Substrate Aggregation Through π-π Stacking in Photoredox Catalysis”
DOI: 10.1002/cphc.202300470
32. S, Fischer, T-T. H. Nguyen, A. Ratzenboeck, H. M. L. Davies, O. Reiser, Org. Lett., 2023, 25, 4411-4415; „Stereoselective Synthesis of Highly Functionalized Cyclohexenes via Strong-Acid-Mediated Endocyclic C-C Bond Cleavage of Monocyclopropanated Cyclopentadiens”
DOI: 10.1021/acs.orglett.3c00935
31. M. Franta, J. Gramüller, P. Dullinger, S. Kaltenberger, D. Horinek, R. M. Gschwind, Angew. Chem. Int, Ed,, 2023, 62, e202301183; „Brønsted Acid Catalysis - Controlling the Competition between Monomeric versus Dimeric Reaction Pathways Enhances Stereoselectivities”
DOI: 10.1002/anie.202301183
30. A. M. Arnold, P. Dullinger, A. Biswas, C. Jandl, D. Horinek, T. Gulder, Nat. Commun, 2023, 14, 813; „Enzyme-like polyene cyclizations catalyzed by dynamic, self-assembled, supramolecular fluoro alcohol-amine clusters”
DOI: 10.1038/s41467-023-36157-0
29. W. Stockerl, R. M. Gschwind, Chem. Commun, 2023, 59, 1325-1328; „Photo enhancement reveals (E,Z) and (Z,Z) configurations as additional intermediates in iminium ion catalysis”
DOI: 10.1039/D2CC05976B
28. Y.-M. Tian, E. Hofmann, W. Silva, D. Touraud, R. M. Gschwind, W. Kunz, B. König, Angew. Chem. Int, Ed, 2023, 62, e202218775; „Enforced Electronic-Donor Complex formation in Water for Photochemical Cross-Coupling”
DOI: 10.1002/anie.202218775
27. S. M. Tiefenthaler, N. Korber, Z. Anorg. Allg. Chem., 2023, 649, e202200286; „[K([2.2.2]-crypt)]K[Pt3(μ2-CO)3(PPh3)3]∙3 NH3 – A New Chini-Type Platinum Carbonyl Complex”
DOI: 10.1002/zaac.202200286
26. J. Bauer, Organometallics, 2022, 41, 321-327; „Influence of Amino Functions on the Coordination Ability of Silyl Ethers and Disiloxanes”
DOI: 10.1021/acs.organomet.1c00663
25. S. M. Tiefenthaler, F. Kleemiss, N. Korber, Z. Anorg. Allg. Chem., 2022, 648, e202100378; „[A([18]crown-6)]2[Pt(CO)3] ⋅ 10 NH3 (A=K, Rb) – A crystal structure containing the long postulated [Pt(CO)3]2−”
DOI: 10.1002/zaac.202100378
24. S. Yakubov, W. J. Stockel, X. Tian, A. Shahin, M. J. P. Mandigma, R. M. Gschwind, J. P. Barham, Chem., Sci., 2022, 13, 14041-14051; „Benzoates as photosensitization catalysts and auxiliaries in efficient, practical, light-powered direct C(sp3)–H fluorinations”
DOI: 10.1039/D2SC05735B
23. A. Falk, J. O. Bauer, Inorg. Chem. 2022, 61, 15576–15588; „Structural and Electronic Effects on Phosphine Chalcogenide Stabilized Silicon Centers in Four-Membered Heterocyclic Cations”
DOI: 10.1021/acs.inorgchem.2c02360
22. F. Babawale, K. Murugesan, R. Narobe, B. König, Org. Lett. 2022, 24, 4793–4797; „Synthesis of Unnatural α-Amino Acid Derivatives via Photoredox Activation of Inert C(sp3)–H Bonds”
DOI: 10.1021/acs.orglett.2c01822
21. J. Gramüller, P. Dullinger, D. Horinek, R. M. Gschwind, Chem. Sci., 2022, 13, 14366-14372; „Bidentate Substrate Binding in Brønsted Acid Catalysis: Structural Space, Hydrogen Bonding and Dimerization”
DOI: 10.1039/D2SC05076E
20. S. Wortmann, R. J. Kutta, P. Nuernberger, Front. Chem. 2022, 10:983342; „Monitoring the photochemistry of a formazan over 15 orders of magnitude in time”
DOI: 10.3389/fchem.2022.983342
19. S. Yakubov, W. J. Stockerl, X. Tian, A. Shahin, M. J. P. Mandigma, R. M. Gschwind, J. P. Barham, Chem. Sci., 2022, 13, 14041-14051; „Benzoates as photosensitization catalysts and auxiliaries in efficient, practical, light-powered direct C(sp3)–H fluorinations”
DOI: 10.1039/D2SC05735B
18. J. Gramüller, M. Franta, R. M. Gschwind, J. Am. Chem. Soc., 2022, 144, 19861-19871; „Tilting the Balance: London Dispersion Systematically Enhances Enantioselectivities in Brønsted Acid Catalyzed Transfer Hydrogenation of Imines”
DOI: 10.1021/jacs.2c07563
17. T. E. Schirmer, B. König, J. Am. Chem. Soc., 2022, 144, 19207-19218; „Ion-Pairing Catalysis in Stereoselective, Light-Induced Transformations”
DOI: 10.1021/jacs.2c04759
16. P. Denk, A. El Maangar, S. Prévost, W. Silva, R. M. Gschwind, T. Zemb, W. Kunz, J. Colloid Interface Science, 2022, 621, 470-488; „Cloud point, auto-coacervation, and nematic ordering of micelles formed by etlene oxide containing carboxylate surfactants”
DOI: 10.1016/j.jcis.2022.04.046
15. A. K. Dutta, S. Park, C. Allacher, A. Abramov, P. Dullinger, K. Kuzmanoska, D. Fritsch, P. Hitzfeld, D. Horinek, J. Rehbein, P. Nuernberger, R. M. Gschwind, A. Breder, Angew. Chem. Int. Ed., 2022, 61, e202208611; „Hydrogen bond-modulated nucleofugality of SeIII species to enable photoredox catalytic semipinacol manifolds”
DOI:10.1002/anie.202208611
14. K. Kristinaityte, A. Mames, M. Pietrzak, F. F. Westermair, W. Silva, R. M. Gschwind, T. Ratajczyk, M. Urba´nczyk, J. Am. Chem. Soc., 2022, 144, 13938-13945; „Deeper insight into photopolymerization: The Synergy of Time-Resolved Non-Uniform Sampling and Diffusion NMR”
DOI: 10.1021/jacs.2c05944
13. J. A. Kelly, V. Streitferdt, M. Dimitrova, F. F. Westermair, R. M. Gschwind, R. Berger, R. Wolf, J. Am. Chem. Soc., 2022, 144, 20434-20431; „Transition-Metal-Stabilised Heavy Tetraphospholide Anions”
DOI: 10.1021/jacs.2c08754
12. R. Eckl, S. Fischer, C. M. Sonnleitner, D. Schmidhuber, J. Rehbein, O. Reiser, ACS Org. Inorg. Au 2022, 2, 169-174; „Stereoselective Synthesis of Biologically Relevant Tetrahydropyridines and Dihydro-2H-pyrans via Ring-Expansion of Monocyclopropanated Heterocycles”
DOI: 10.1021/acsorginorgau.1c00042
11. M. Zabka, R.M. Gschwind, Eur. J. Org. Chem. 2022, 2022, 26, e202200048; „Substrate Photoswitching for Rate Enhancement of an Organocatalytic Cyclization Reaction”
DOI: 10.1002/ejoc.202200048
10. T. Götz, A. Falk, J. O. Bauer, Chem. Eur. J. 2022, 28, e202103531; „Molecular Scissors for Tailor-Made Modification of Siloxane Scaffolds”
DOI: 10.1002/chem.202103531
9. N. Fontana, N. A. Espinosa-Jalapa, M. Seidla, J. O. Bauer, Chem. Commun., 2022, 58, 2144-2147; „Hidden silylium-type reactivity of a siloxane-based phosphonium–hydroborate ion pair”
DOI: 10.1039/D1CC07016A
8. G. Hierlmeier, R. Wolf, Organometallics, 2022, 41, 776-784; „Bulking up CpBIG: A Penta-Terphenyl Cyclopentadienyl Ligand”
DOI: 10.1021/acs.organomet.2c00009
7. M. Till, V. Streitferdt, D. J. Scott, M. Mende, R.M. Gschwind, R. Wolf, Chem. Commun., 2022, 58, 1100-1103; „Photochemical transformation of chlorobenzenes and white phosphorus into arylphosphines and phosphonium salts”
DOI: 10.1039/d1cc05691c
6. S. Wortmann, S. Schloeglmann, P. Nuernberger, J. Org. Chem. 2022, 87, 1745-1755; „Sensitivity of Isomerization Kinetics of 1,3,5-Triphenylformazan on Cosolvents Added to Toluene”
DOI: 10.1021/acs.joc.1c01928
5. M. Zabka, R.M. Gschwind, Chem. Sci. 2021, 12, 15263-15272; "Ternary Complexes of Chiral Disulfonimides in Transfer-Hydrogenation of Imines: The Relevance of Late Intermediates in Ion Pair Catalysis"
DOI: 10.1039/D1SC03724B
4. M.J. Margeson, F. Seeberger, J. A. Kelly, J. Leitl, P. Coburger, R. Szlosek, C. Müller, R Wolf, ChemCatChem 2021, 13, 3761-3764; „Expedient Hydrofunctionalisation of Carbonyls and Imines Initiated by Phosphacyclohexadienyl Anions”
DOI: 10.1002/cctc.202100651
3. S. Karbalaei Khani, B. Geissler, E. Engelage, P. Nuernberger, C. Hättig, Phys. Chem. Chem. Phys. 2021, 23, 7480–7494; „Tracing absorption and emission characteristics of halogen-bonded ion pairs involving halogenated imidazolium species”
DOI: 10.1039/d1cp00009h
2. N. Berg, S. Bergwinkl, P. Nuernberger, D. Horinek, R.M. Gschwind, J. Am. Chem. Soc., 2021, 143, 724-735; „Extended Hydrogen Bond Networks for Effective Proton-Coupled Electron Transfer (PCET) Reactions: The Unexpected Role of Thiophenol and Its Acidic Channel in Photocatalytic Hydroamidations”
DOI: 10.1021/jacs.0c08673
1. J.. Kelly, J. Gramüller, R. Wolf, R.M. Gschwind, Dalton Trans., 2021, 50, 13985-13992; „Low-oxidation state cobalt-magnesium complexes: ion-pairing and reactivitys”
DOI: 10.1039/d1dt02621f
For publications from single PI's -> see homepage of the supervisor
J. Leitl, A. R. Jupp, E. R. M. Habraken, V. Streitferdt, P. Coburger, R. M. Gschwind, C. Müller, J. C. Slootweg, R. Wolf, Chem. Eur. J. 2020, 26, 7788-780; “A phosphinine-derived 1-phospha-7-bora-norbornadiene: frustrated Lewis pair type activation toward triple bonds“
DOI: 10.1002/chem.202000266
S. Wang, N. Lokesh, J. Hioe, R. Gschwind, B. König; Chem Sci. 2019, 10, 4580-4587; “Photoinitiated Carbonyl‐Metathesis: Deoxygenative Reductive Olefination of Aromatic Aldehydes via Photoredox Catalys“
DOI: 10.1039/C9SC00711C
D. Petzold, P. Nitschke, F. Brandl, V. Scheidler, B. Dick, R. M. Gschwind, B. König; Chem. Eur. J. 2019, 25, 361-366; “Visible Light Mediated Liberation and in situ Conversion of Fluorophosgene”
DOI: 10.1002/chem.201804603
A. C. Kneuttinger, K. Straub, P. Bittner, N. Simeth, A. Bruckmann, F. Busch, C. Rajendran, E. Hupfeld, V. H. Wysocki, D. Horinek, B. König, R. Merkl, R. Sterner; Cell Chem. Biol. 2019, 26, 1501-1514; ”Light-Regulation of Enzyme Allostery through Photo-Responsive Unnatural Amino Acids”
DOI: 10.1016/j.chembiol.2019.08.006
F. Hastreiter, C. Lorenz, J. Hioe, S. Gärtner, L. Nanjundappa, N. Korber, R. M. Gschwind, Angew. Chem. Int. Ed., 2019, 58, 3133-3137; ”Elusive Zintl Ions [µ HSi4]3− and [Si5]2− in Liquid Ammonia: Protonation States, Sites, and Bonding Situation by NMR and Theory”
DOI: 10.1002/ange.201812955
T. Pongratz, P. Kibies, L. Eberlein, N. Tielker, C. Hölzl, S. Imoto, M. Beck Erlach, S. Kurrmann, P. H. Schummel, M. Hofmann, O. Reiser, R. Winter, W. Kremer, H. R. Kalbitzer, D. Marx, D. Horinek, S. M. Kast Biophys. Chem. 2019, 106258; ”Pressure-dependent electronic structure calculations using integral equation-based solvation models”
DOI: 10.1016/j.bpc.2019.106258
S. Kerres, S. Malcherek, J. Rehbein, O. Reiser, Adv. Synth. Catal. 2019, 361, 1400-1407; ”Visible Light Mediated Synthesis of enantiopure γ-Cyclobutane Amino and 3-(Aminomethyl)-5-phenylpentanoic Acids”
DOI: 10.1002/adsc.201801413
U. Lennert, P.B. Arockiam, V. Streitferdt, D.J. Scott, C. Rödl, R.M. Gschwind, R. Wolf, Nat. Cat. 2019, 2, 1101-1106; “Direct Catalytic Transformation of White Phosphorus into Aryl Phosphines and Phosphonium Salts“
DOI: 10.1038/s41929-019-0378-4
J. Leitl
J. Leitl, M. Marquardt, P. Coburger, D. J. Scott, V. Streitferdt, R. M. Gschwind, C. Müller, R. Wolf, Angew. Chem. Int. Ed. 2019, 58, 15407-15411; “Facile C=O Bond Splitting of Carbon Dioxide Induced by Metal‑Ligand Cooperativity in a Phosphinine Iron(0) Complex“
DOI: 10.1002 / anie.201909240
L. Marzo, S. K. Pagire, O. Reiser, B. König, Angew. Chem. Int. Ed. 2018, 57, 10034 – 10072; ”Visible-Light Photocatalysis: Does it make a difference in Organic Synthesis?”
DOI; 10.1002/anie.201709766
C. Lorenz, F. Hastreiter, J. Hioe, L. Nanjundappa, S. Gärtner, N. Korber, R.M. Gschwind, Angew. Chem. Int. Ed. 2018, 57, 12956-12960; “Structure of [HSi₉]³⁻ in Solid State and Its Unexpectedly High Dynamics in Solution”
DOI: 10.1002/anie.201807080
R.J. Wilson, F. Hastreiter, K. Reiter, P. Büschelberger, R. Wolf, R.M. Gschwind, F. Weigend, S. Dehnen, Angew. Chem. Int. Ed. 2018, 57, 15359-15363; “[Co@Sn6Sb6]3−: An Off‐Center Endohedral 12‐Vertex Cluster”
DOI: 10.1002/anie.201807180
T. Föll, J. Rehbein, O. Reiser, Org. Lett. 2018, 20, 5794-5798; “Ir(ppy)3-Catalyzed, Visible-Light-Mediated Reaction of α-Chloro Cinnamates with Enol Acetates: An Apparent Halogen Paradox”
DOI: 10.1021/acs.orglett.8b02484
A. Hossain, A. Vidyasagar, C. Eichinger, C. Lankes, J. Phan, J. Rehbein, O. Reiser, Angew. Chem. Int. Ed. Engl. 2018, 57, 8288-8292; ”Visible-Light-Accelerated Copper(II) Catalyzed Regio- and Chemoselective Oxo-Azidation of Vinyl Arenes”
DOI: 10.1002/anie.201801678
A. Das, M. Maity, S. Malcherek, B. König, J. Rehbein, Beilstein J. Org. Chem. 2018, 14, 2520–2528; ”Synthesis of aryl sulfides via radical–radical cross coupling of electron-rich arenes using visible light photoredox catalysis”
DOI: 10.3762/bjoc.14.228
A. Eisenhofer, J. Hioe, R. Gschwind, B. König, Eur. J. Org. Chem. 2017, 2194–2204; ”Photocatalytic Phenol-Arene C-C and C-O Cross-Dehydrogenative Coupling”
DOI: 10.1002/ejoc.201700211
T. Hering, B. Mühldorf, R. Wolf, B, König, Angew. Chem. Int. Ed. 2016, 55, 5342-5345; "Halogenase-Inspired Oxidative Chlorination Using Flavin Photocatalysis"
DOI: 10.1002/anie.201600783
H. Bartling, A. Eisenhofer, B. König, R.M. Gschwind, J. Am. Chem. Soc. 2016, 138, 11860-11871; “The Photocatalyzed Aza-Henry Reaction of N-Aryltetrahydroisoquinolines: Comprehensive Mechanism, H•- versus H+-Abstraction, and Background Reactions”
DOI: 10.1021/jacs.6b06658
R. Frach, P. Kibies, S. Böttcher, T. Pongratz, S. Strohfeldt, S. Kurrmann, J. Koehler, M. Hofmann, W. Kremer, H. R. Kalbitzer, O. Reiser, D. Horinek, S. M. Kast, Angew. Chem. Int. Ed. 2016, 55, 8757; „The Chemical Shift Baseline for High-Pressure NMR Spectroscopy of Proteins“
DOI: 10.1002/anie.201602054.
H. Jangra, M.H. Haindl, F. Achrainer, J. Hioe, R.M. Gschwind, H. Zipse, Chem. Eur. J. 2016, 22, 13328-13335; “Conformational Preferences in Small Peptide Models: The Relevance of cis/trans-Conformations”
DOI: 10.1002/chem.201601828
F. Fendt, C. Koch, M. Neumeier, S. Gärtner, R.M. Gschwind, N. Korber, Chem. Eur. J. 2015, 21, 14539-14544; “Stability and Conversion of Tin Zintl Anions in Liquid Ammonia Investigated by NMR Spectroscopy”
DOI: 10.1002/chem.201501100
S. Gärtner, T. Gärtner, R.M. Gschwind, N. Korber, Acta Cryst. 2014, E70, 555-558; „About the polymorphism [Li(C4H8O)3]I:crystal structures of trigonal and tetragonal polymorphs”
DOI: 10.1107/S160053681402529X
J. Daďová, S. Kümmel, C. Feldmeier, J. Cibulkova, R. Pazout, J. Maixner, R.M. Gschwind, B. König, R. Cibulka, Chem. Eur. J. 2013, 19, 1066-1075; “Aggregation Effects in Visible-Light Flavin Photocatalysts: Synthesis, Structure, and Catalytic Activity of 10-Arylflavins”
DOI: 10.1002/chem.201202488
M. Neumeier, F. Fendt, S. Gärtner, C. Koch, T. Gärtner, N. Korber, R.M. Gschwind, Angew. Chem. Int. Ed. 2013, 52, 4483-4486; “Detection of the Elusive Highly Charged Zintl Ions Si4(4-) and Sn4(4-) in Liquid Ammonia by NMR Spectroscopy”
DOI: 10.1002/anie.201209578
T. Thaler, B. Haag, A. Gavryushin, K. Schober, E. Hartmann, R.M. Gschwind, H. Zipse, P. Mayer, P. Knochel, Nature Chemistry 2010, 2, 125-130; “Highly diastereoselective Csp3–Csp2 Nis cross-coupling with 1,2-, 1,3- and 1,4-substituted cyclokylzinc compounds“
DOI: 10.1038/NCHEM.505
M. Schmid, M. Fleischmann, V. D´Elia, O. Reiser, W. Gronwald, R.M. Gschwind, ChemBioChem, 2009, 10, 440–444; „RDCs in Short Peptidic Foldamers: Combined Analyses of Backbone and Side Chain Conformations and Evaluation of Structure Coordinates of Rigid Unnatural Amino Acids”
DOI: 10.1002/cbic.200800736