Search

Search results

• "An NMR Spectroscopy View on London Dispersion in Catalysis: Detection, Quantification, and Application in Ion Pair and Transition Metal Catalysis", Gramüller, Gschwind, 2023

  Publication

  The energetic contribution of London dispersion (LD) can cover a broad range from very few to hundreds of kJ mol-1 for extended interaction interfaces...

  Publication on epub.uni-regensburg.de: "An NMR Spectroscopy View on London Dispersion in Catalysis: Detection, Quantification, and Application in Ion Pair and Transition Metal Catalysis" (external link, opens in a new window)

• "Highly Acidic N-Triflylphosphoramides as Chiral Brønsted Acid Catalysts: The Effect of Weak Hydrogen Bonds and Multiple Acceptors on Complex Structures and Aggregation", Hecht, Dullinger, Silva, Horinek, Gschwind, 2024

  Publication

  N-Triflylphosphoramides (NTPAs) represent an important catalyst class in asymmetric catalysis due to their multiple hydrogen bond acceptor sites and...

  Publication on epub.uni-regensburg.de: "Highly Acidic N-Triflylphosphoramides as Chiral Brønsted Acid Catalysts: The Effect of Weak Hydrogen Bonds and Multiple Acceptors on Complex Structures and Aggregation" (external link, opens in a new window)

• "Accelerated photochemical reactions at oil-water interface exploiting melting point depression", Tian, Silva, Gschwind, König, 2024

  Publication

  Water can accelerate a variety of organic reactions far beyond the rates observed in classical organic solvents. However, using pure water as a...

  Publication on epub.uni-regensburg.de: "Accelerated photochemical reactions at oil-water interface exploiting melting point depression" (external link, opens in a new window)

• "Reactivity of Superbasic Carbanions Generated via Reductive Radical‐Polar Crossover in the Context of Photoredox Catalysis", Grotjahn, Graf, Zelenka, Pattanaik, Müller, Kutta, Rehbein, Roithová, Gschwind, Nuernberger, König, 2024

  Publication

  Photocatalytic reactions involving a reductive radical-polar crossover (RRPCO) generate intermediates with carbanionic reactivity. Many of these...

  Publication on epub.uni-regensburg.de: "Reactivity of Superbasic Carbanions Generated via Reductive Radical‐Polar Crossover in the Context of Photoredox Catalysis" (external link, opens in a new window)

• "Chiral Diselenophosphoric Acids for Ion Pair Catalysis: A Novel Approach to Enhance Both Proton Donating and Proton Accepting Properties", Eder, Antonov, Tupikina, Gschwind, 2024

  Publication

  The activation of poorly reactive substrates via strong chiral acids is a central topic in asymmetric ion pair catalysis these days. Despite highly...

  Publication on epub.uni-regensburg.de: "Chiral Diselenophosphoric Acids for Ion Pair Catalysis: A Novel Approach to Enhance Both Proton Donating and Proton Accepting Properties" (external link, opens in a new window)

• "Protodefluorinated Selectfluor® Aggregatively Activates Selectfluor® for Efficient Radical C(sp3)−H Fluorination Reactions", Yakubov, Dauth, Stockerl, Menezes da Silva, Gschwind, Barham, 2024

  Publication

  Efficient fluorination reactions are key in the late-stage functionalization of complex molecules in medicinal chemistry, in upgrading chemical...

  Publication on epub.uni-regensburg.de: "Protodefluorinated Selectfluor® Aggregatively Activates Selectfluor® for Efficient Radical C(sp3)−H Fluorination Reactions" (external link, opens in a new window)

• "Unravelling White Phosphorus: Experimental and Computational Studies Reveal the Mechanisms of P4 Hydrostannylation", Scott, Cammarata, Westermair, Coburger, Duvinage, Janssen, Uttendorfer, Beckmann, Gschwind, Wolf, 2024

  Publication

  The hydrostannylation of white phosphorus (P4) allows this crucial industrial precursor to be easily transformed into useful P1 products via direct,...

  Publication on epub.uni-regensburg.de: "Unravelling White Phosphorus: Experimental and Computational Studies Reveal the Mechanisms of P4 Hydrostannylation" (external link, opens in a new window)

• "Promoting enzyme catalysis via azobenzene facilitated vibrational energy transfer", Lahmy, Hiefinger, Zeqiri, Mandl, Straub, Stockerl, Gschwind, Rudack, König, Hupfeld, 2024

  Publication

  Besides its capability to switch between two configurations, azobenzene converts light energy to vibrational energy (VE). Incorporation of the...

  Publication on epub.uni-regensburg.de: "Promoting enzyme catalysis via azobenzene facilitated vibrational energy transfer" (external link, opens in a new window)

• "Liquid Ammonia: More than an Innocent Solvent for Zintl Anions", Gärtner, Witzmann, Lorenz-Fuchs, Gschwind, Korber, 2024

  Publication

  Liquid ammonia as the original solvent for Zintl anions has been replaced by easier to handle or more versatile solvents in most recent Zintl...

  Publication on epub.uni-regensburg.de: "Liquid Ammonia: More than an Innocent Solvent for Zintl Anions" (external link, opens in a new window)

• "Regio-, diastereo- and enantioselectivity in the photocatalytic generation of carbanions via hydrogen atom transfer and reductive radical-polar crossover", Grotjahn, Müller, Pattanaik, Falk, Barison, Bauer, Rehbein, Gschwind, König, 2024

  Publication

  A sequence involving photocatalytic hydrogen atom transfer (HAT), reductive radical-polar crossover (RRPCO), and protonation/deuteration for...

  Publication on epub.uni-regensburg.de: "Regio-, diastereo- and enantioselectivity in the photocatalytic generation of carbanions via hydrogen atom transfer and reductive radical-polar crossover" (external link, opens in a new window)