Publikationen AG Gärtner

Cover Feature: Trigonal Bipyramidal Clusters [Tl₅]⁷⁻: Synthesis and Characterization of the Zintl Phase K_7−xA_xTl₅ (A = Rb, Cs; 0 < x ≤ 2.35)

V. F. Schwinghammer, T. Kovářík, I. G. Shenderovich, J. Minár, S. Gärtner, Chem. Eur. J., 2025, 31, e70454.

DOI:   10.1002/chem.70454 (externer Link, öffnet neues Fenster)

Front Cover: Synthesis and characterization of ternary trielides Na₇KTr₄ [Tr=In or Tl] including [Tr₄]^8- tetrahedra

M. Janesch, V.F. Schwinghammer, I.G. Shenderovich, S. Gärtner, Z. Anorg. Allg. Chem., 649, e202300211. 

DOI:   10.1002/zaac.202300211 (externer Link, öffnet neues Fenster)

Front Cover: Investigations on Tetragonally Distorted Sodium Thallide NaTl‐tI8

S. Tiefenthaler, M. Schlosser, F. Pielnhofer, I. G. Shenderovich, A. Pfitzner, S. Gärtner, Z. Anorg. Allg. Chem. 646, 77-77 (2020). 

DOI:   10.1002/zaac.202070031  (externer Link, öffnet neues Fenster)

Endohedral [Au@In10]^9- Cluster: Synthesis and Characterization of Na_3+xA^6-xIn₁₀Au (x=0, 0.25; A=Rb, Cs)

M. Janesch, F. Pielnhofer, M. Dušek, I.G. Shenderovich, S. Gärtner, Inorg. Chem., 2026, 65, 6, 3343–3351.

DOI:   10.1021/acs.inorgchem.5c04619 (externer Link, öffnet neues Fenster)

A New Thallide Auride Double Salt: Cs_3.4K_4.6[Au][Tl₇] Featuting [Tl₇]^7- Zintl Clusters

V.F. Schwinghammer, S. Gärtner, Z. Anorg. Allg. Chem.,2025, 652, e202500180.

DOI:   10.1002/zaac.202500180 (externer Link, öffnet neues Fenster)

Trigonal Bipyramidal Clusters [Tl₅]⁷⁻:

Synthesis and Characterization of the Zintl Phase K_7−xA_xTl₅ (A=Rb,Cs; 0 < x ≤ 2.35)

V. F. Schwinghammer, T. Kovářík, I. G. Shenderovich, J. Minár, S. Gärtner, Chem. Eur. J., 2025, 31, e02837.

DOI: 10.1002/chem.202502837 (externer Link, öffnet neues Fenster)

VIP : Icosahedral Clusters [In@Tr₁₂]^10– : Synthesis, Characterization, and Electronic Structure Investigations of Na₄A₆Tr₁₃ (A = Rb, Cs; Tr = In, Tl)

M. Janesch, A. Karttunen, S. Gärtner, Eur. J. Inorg. Chem.,2025, 28, e202500347.

DOI:   10.1002/ejic.202500347 (externer Link, öffnet neues Fenster)

Approaching Hypothetical RbTl in Experiments and Theory – 

X-ray Structure Determination of Cs_1–xRb_xTl (x = 0.18, 0.42) and a Solid Solution K_1–xRb_xTl (x ≤ 0.69)

V.F. Schwinghammer, S.A. Khan, S.M. Tiefenthaler, T. Kovářík, J. Minár, S. Gärtner, Inorg. Chem.,2025, 64, 14, 6879-6887. 

DOI:   10.1021/acs.inorgchem.4c05305 (externer Link, öffnet neues Fenster)

[Tl₇]^7- Clusters in Mixed Alkali Metal Thallides Cs_7.29K_5.71Tl₁₃ and Cs_3.45K_3.55Tl₇

V.F. Schwinghammer, S. Gärtner, Inorg. Chem.,2024, 63, 43, 20078-20082

DOI:   10.1021/acs.inorgchem.3c04034 (externer Link, öffnet neues Fenster)

Synthesis and characterization of ternary trielides Na₇KTr₄ [Tr=In or Tl] including [Tl₄]^8- Tetrahedra

M. Janesch, V.F. Schwinghammer, I.G. Shenderovich, S. Gärtner, Z. Anorg. Allg. Chem., 2023, e202300112. 

DOI:   10.1002/zaac.202300112 (externer Link, öffnet neues Fenster)

Na₇RbTl⁴ — A New Ternary Zintl Phase Containing [Tl₄]^8– Tetrahedra

V.F. Schwinghammer, M. Janesch, N. Korber, S. Gärtner, Z. Anorg. Allg. Chem.,  2022, e202200332.

DOI:   10.1002/zaac.202200332 (externer Link, öffnet neues Fenster)

Single Crystal X-Ray Structure Analyses of Binary and Ternary Compounds A₄₉Tl_108+x (A=K, Rb, Cs; x=0-1.76); Related to the K₄₉Tl₁₀₈ Type Structure

V.F. Schwinghammer, M. Janesch, F. Kleemiss, S. Gärtner, Z. Anorg. Allg. Chem. 648, 1-7 (2022) 

DOI:   10.1002/zaac.202200117

The Role of Different Alkali Metals in the A₁₅Tl₂₇ Type Structure and the Synthesis and X-ray Structure Analysis of a New Substitutional Variant Cs_14.53Tl_28.4  

V.F. Schwinghammer, S.M. Tiefenthaler, S. Gärtner, Materials 14, 7512 (2021)   

DOI:   10.3390/ma14247512 (externer Link, öffnet neues Fenster)

Spotlight on Alkali Metals: The Structural Chemistry of Alkali Metal Thallides

S. Gärtner, Crystals 10, 1013 (2020) 

DOI:   10.3390/cryst10111013 (externer Link, öffnet neues Fenster)

Investigations on Tetragonally Distorted Sodium Thallide NaTl‐tI8

S. Tiefenthaler, M. Schlosser, F. Pielnhofer, I. G. Shenderovich, A. Pfitzner, S. Gärtner, Z. Anorg. Allg. Chem. 646, 82 (2020) 

DOI:   10.1002/zaac.201900269 (externer Link, öffnet neues Fenster)

Synthesis of the Tetragonal Phase of Zintl’s NaTl and its Structure Determination from Powder Diffraction Data

S. Tiefenthaler, N. Korber, S. Gärtner, Materials 12, 1356 (2019) 

DOI:   10.3390/ma12081356 (externer Link, öffnet neues Fenster)

Elusive Zintl Ions [μ HSi₄]³⁻ and [Si₅]²⁻ in Liquid Ammonia: Protonation States, Sites, and Bonding Situation by NMR and Theory

F. Hastreiter, C. Lorenz, J. Hioe, S. Gärtner, L. Nanjundappa, N. Korber, R. M. Gschwind, Angew. Chem. 58, 3133 (2019)

DOI:   10.1002/anie.201812955 (externer Link, öffnet neues Fenster)

Structural Chemistry of Halide including Thallides A₈Tl₁₁X_1−n  (A = K, Rb, Cs; X = Cl, Br; n = 0.1–0.9)

S. Gärtner, S. Tiefenthaler, N. Korber, S. Stempfhuber, B. Hischa, Crystals 8, 319 (2018) 

DOI:   10.3390/cryst8080319 (externer Link, öffnet neues Fenster)

Structure of [HSi₉]³⁻ in Solid State and Its Unexpectedly High Dynamics in Solution

C. Lorenz, F. Hastreiter, J. Hioe, L. Nanjundappa, S. Gärtner, N. Korber, R. M. Gschwind, Angew. Chem. 130, 13138 (2018)

DOI:   10.1002/ange.201807080 (externer Link, öffnet neues Fenster)

Ammoniates of Zintl Phases: Similarities and Differences of Binary Phases A₄E₄ and Their Corresponding Solvates

C. Lorenz, S. Gärtner, N. Korber, Crystals 8, 276 (2018) 

DOI:   10.3390/cryst8070276 (externer Link, öffnet neues Fenster)

Dinuclear indium and thallium diyls: biscarbenoids or metal cluster?

M. Desat, S. Gaertner, R. Kretschmer, Chem.Commun. 53, 1510-1513 (2017) 

DOI:   10.1039/C6CC09488K (externer Link, öffnet neues Fenster)

Si₄⁴⁻ in Solution - First Solvate Crystal Structure of the Ligand-​free Tetrasilicide Tetraanion in Rb₁.₂K₂.₈Si₄ ⋅ 7 NH₃

C. Lorenz, S. Gaertner, N. Korber, Z. Anorg. Allg. Chem. 643, 141-145 (2017)

DOI:   10.1002/zaac.201600336 (externer Link, öffnet neues Fenster)

Selective P4 Activation by a Highly Reduced Cobaltate: Synthesis of Dicobalt Tetraphosphido Complexes

S. Pelties, T. Maier, D. Herrmann, B. de Bruin, C.  Rebreyend, S. Gaertner, I. G. Shenderovich, R. Wolf,  Chem. Eur. J. 23, 6094-6102 (2017)

DOI:   10.1002/chem.201603296 (externer Link, öffnet neues Fenster)

Co-​crystallization of Half-​sandwich (RM,​RC)​/(SM,​RC)​-​Diastereomers in Single Crystals

H. Brunner, T. Tsuno, M. Bodensteiner, S. Gaertner, C. Miyahara, S.  Ito, T. Kurosawa, K. Koyama, Eur. J. Inorg. Chem. 2016, 5405-5410 

DOI:   10.1002/ejic.201600962 (externer Link, öffnet neues Fenster)

The first chelate-free crystal structure of a silicide transition metal complex K₀.₂₈Rb₇.₇₂[Si₉Ni(CO)₂]₂⋅16NH₃

S. Gärtner, M. Hamberger, N. Korber, Crystals 5, 275-282 (2015)

DOI:   10.3390/cryst5030275 (externer Link, öffnet neues Fenster)

Stability and Conversion of Tin Zintl Anions in Liquid Ammonia Investigated by NMR Spectroscopy

F. Fendt, C. Koch, M. Neumeier, S. Gärtner, R. M. Gschwind, N. Korber, Chem. Eur. J. 21, 14539-14544 (2015)

DOI:   10.1002/chem.201501100 (externer Link, öffnet neues Fenster)

About the polymorphism of [Li(C₄H₈O)₃]I: crystal structures of trigonal and tetragonal polymorphs

S. Gärtner, T. Gärtner, R. M. Gschwind, N. Korber, Acta Cryst. E70, 555-558 (2014)

DOI:   10.1107/S160053681402529X (externer Link, öffnet neues Fenster)

Coordination preferences of the alkali cations sodium and caesium in the mixed-cationic Zintl ammoniate Cs₃.₂Na₀.₈Ge₉·5.3NH₃

S. Gärtner, C. Suchentrunk, N. Korber, Acta Crystallogr. C70, 1036-1039 (2014)

DOI: 10.1107/S2053229614021998 (externer Link, öffnet neues Fenster)

Reaction of Sn₄⁴⁻ in liquid ammonia: the formation of Rb₆[(η²-Sn₄)Zn(η³-Sn₄)]·5NH₃

F. Fendt, C. Koch, S. Gärtner, N. Korber, Dalton Trans. 42, 15548-15550 (2013)

DOI:   10.1039/C3DT51932E (externer Link, öffnet neues Fenster)

Zintl Anions 

S. Gärtner, N. Korber, in: K. Poeppelmeier (Ed.), J. Reedijk (Ed.), Main-Group Elements, Comprehensive Inorganic Chemistry II (Second Edition) 1, Elsevier Ltd., Amsterdam Oxford Waltham (2013) S. 251-267; 

ISBN 978-0-08-096529-1

DOI:   10.1016/B978-0-08-097774-4.00110-8 (externer Link, öffnet neues Fenster)

NMR-spektroskopische Detektion der schwer zu fassenden hochgeladenen Zintl-Ionen Si₄⁴⁻ und Sn₄⁴⁻ in flüssigem Ammoniak

M. Neumeier, F. Fendt, S. Gärtner, C. Koch, T. Gärtner, N. Korber, R. M. Gschwind, Angew. Chem. 125, 4579-4582 (2013)

DOI:   10.1002/ange.201209578 (externer Link, öffnet neues Fenster)

[Rb(18-crown-6)][Rb([2.2.2]-cryptand)]Rb₂Sn₉·5NH₃

S. Gärtner, N. Korber, Acta Crystallogr. E67, m613-m614 (2011)

DOI:   10.1107/S1600536811013997 (externer Link, öffnet neues Fenster)

Polyanions of Group 14 and Group 15 elements in alkali and alkaline earth metal solid state compounds and solvate structures 

S. Gärtner, N. Korber, in: T. F. Fässler (Ed.), Zintl Ions, Structure and Bonding 140, Springer, Berlin Heidelberg (2011) S. 25-57 

ISBN 978-3-642-21180-5

DOI:   10.1007/430_2011_43 (externer Link, öffnet neues Fenster)

Dissolving Silicides: Syntheses and Crystal Structures of New Ammoniates Containing Si₅²⁻ and Si₉⁴⁻ Polyanions and the Role of Ammonia of Crystallisation

S. Joseph, C. Suchentrunk, N. Korber, Z. Naturforsch. 65b, 1059-1065 (2010)

PDF (externer Link, öffnet neues Fenster)

Chemie mit substituentenfreien Silicium-Clustern in Lösung – ein Übergangsmetallkomplex eines Polysilicid-Anions

S. Joseph, M. Hamberger, F. Mutzbauer, O. Härtl, M. Meier, N. Korber, Angew. Chem. 121, 8926-8929 (2009)

DOI:   10.1002/ange.200904242 (externer Link, öffnet neues Fenster)

Si₉⁴⁻ Anions in Solution - Structures of the Solvates Rb₄Si₉·4.75NH₃ and [Rb(18-crown-6)]Rb₃Si₉⋅4NH₃, and Chemical Bonding in Si₉⁴⁻

S. Joseph, C. Suchentrunk, F. Kraus, N. Korber, Eur. J. Inorg. Chem., 4641-4647 (2009)

DOI:   10.1002/ejic.200900230 (externer Link, öffnet neues Fenster)